A fully recyclable heterogenized Cu catalyst for the general carbene transfer reaction in batch and flow† †Electronic supplementary information (ESI) available: Experimental details of catalyst preparation, catalytic experiments and identification of the products. See DOI: 10.1039/c4sc03277b Click here for additional data file.

A fully recyclable heterogenized Cu catalyst for the general carbene transfer reaction in batch and flow.

A polystyrene-linked tris(triazolyl)methanecopper(i) cationic catalyst operates under heterogeneous conditions for the reaction of ethyl diazoacetate (EDA) with an array of substrates. Carbon-hydrogen as well as X-H (X = O, N) functionalization derived from the formal transfer of the carbene moiety (:CHCO2Et) from the copper center and subsequent insertion have been achieved, the reactions perm...

Copper doped ceria porous nanostructures towards a highly efficient bifunctional catalyst for carbon monoxide and nitric oxide elimination† †Electronic supplementary information (ESI) available: details of the experiments; XRD, SEM, TGA and EDX patterns of the products; the CO catalytic activity of CeO2:Cu2+ porous nanomaterials. See DOI: 10.1039/c5sc00129c Click here for additional data file.

Nanophase-separated Ni3Nb as an automobile exhaust catalyst† †Electronic supplementary information (ESI) available: Demonstration procedure, experimental and characterization details. See DOI: 10.1039/c6sc05473k Click here for additional data file. Click here for additional data file.

Nucleophilic addition and substitution at coordinatively saturated boron by facile 1,2-hydrogen shuttling onto a carbene donor† †Electronic supplementary information (ESI) available: General experimental details, characterization data for all reported compounds and details of the DFT calculations. CCDC 1563216–1563221. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc03193a Click here for additional data file. Click here for additional data file.

Identifying lead hits in catalyst discovery by screening and deconvoluting complex mixtures of catalyst components† †Electronic supplementary information (ESI) available: Experimental procedures and spectral data. See DOI: 10.1039/c5sc00268k Click here for additional data file.

A reaction-economic combinatorial strategy is described for lead hit identification in catalyst discovery efforts directed towards a specific transformation. Complex mixtures of rationally chosen precatalysts and ligands are screened against various reaction parameters to identify lead conditions in a small number of reactions. Iterative deconvolution of the resulting hits identifies which comp...